A supramolecular cation in an electrically conducting nickel dithiolate salt

被引：22

作者：

Akutagawa, T

Nakamura, T

Inabe, T

Underhill, AE

机构：

[1] HOKKAIDO UNIV,FAC SCI,DEPT CHEM,SAPPORO,HOKKAIDO 060,JAPAN

[2] UNIV WALES,DEPT CHEM,BANGOR LL57 2UW,GWYNEDD,WALES

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1997年 / 7卷 / 02期

关键词：

D O I：

10.1039/a607600k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel dimeric penta-coordinated ion cavity of [Li+](2) [12-crown-4-ether](3) has been formed in the highly conducting Ni(dmit)(2) salt. This salt showed a room-temperature conductivity of 30 S cm(-1) and exhibited a semiconductor-semiconductor phase transition on the application of pressure or on lowering the temperature.

引用

收藏

页码：183 / 185

页数：3

相关论文

共 20 条

[1]

AKUTAGAWA T, IN PRESS SYNTH MET

[2] MOLECULAR-METALS AND SUPERCONDUCTORS DERIVED FROM METAL-COMPLEXES OF 1,3-DITHIOL-2-THIONE-4,5-DITHIOLATE (DMIT) [J].

CASSOUX, P ;

VALADE, L ;

KOBAYASHI, H ;

KOBAYASHI, A ;

CLARK, RA ;

UNDERHILL, AE .

COORDINATION CHEMISTRY REVIEWS, 1991, 110 (01) :115-160

[3]

CONWELL EM, 1988, SEMICONDUCT SEMIMET, V27, P293

[4] Intermolecular interactions in the molecular ferromagnetic NH4Ni(mnt)(2)center dot H2O [J].

Coomber, AT ;

Beljonne, D ;

Friend, RH ;

Bredas, JL ;

Charlton, A ;

Robertson, N ;

Underhill, AE ;

Kurmoo, M ;

Day, P .

NATURE, 1996, 380 (6570) :144-146

[5] SUPRAMOLECULAR CONTROL OF MOLECULAR ELECTRONIC BEHAVIOR OF TCNQ- SALTS [J].

GROSSEL, MC ;

WESTON, SC .

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1992, 5 (08) :533-539

[6] ISOLATED FREE-RADICAL PAIRS IN RB+ 18-CROWN-6 TETRACYANOQUINODIMETHANE SINGLE-CRYSTALS [J].

GROSSEL, MC ;

EVANS, FA ;

HRILJAC, JA ;

MORTON, JR ;

LEPAGE, Y ;

PRESTON, KF ;

SUTCLIFFE, LH ;

WILLIAMS, AJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (05) :439-441

[7] ON THE CRYSTAL-STRUCTURE OF THE (1-1) COMPLEX BETWEEN LITHIUM THIOCYANATE AND 1,4,7,10-TETRAOXACYCLODODECANE AT ROOM-TEMPERATURE [J].

GROTH, P .

ACTA CHEMICA SCANDINAVICA SERIES A-PHYSICAL AND INORGANIC CHEMISTRY, 1981, 35 (06) :463-465

[8] X-RAY CRYSTAL-STRUCTURES OF THE DIPHENYLPHOSPHIDE AND DIPHENYLARSENIDE ANIONS - USE OF A CROWN ETHER TO EFFECT COMPLETE METAL CATION AND ORGANOMETALLOID ANION SEPARATION [J].

HOPE, H ;

OLMSTEAD, MM ;

POWER, PP ;

XU, XJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (03) :819-821

[9] ISOLATION AND X-RAY CRYSTAL-STRUCTURES OF THE MONONUCLEAR CUPRATES (CUME2]-, [CUPH2]-, AND [CU(BR)CH(SIME3)2]- [J].

HOPE, H ;

OLMSTEAD, MM ;

POWER, PP ;

SANDELL, J ;

XU, X .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (14) :4337-4338

[10] THERMODYNAMIC AND KINETIC DATA FOR CATION MACROCYCLE INTERACTION [J].

IZATT, RM ;

BRADSHAW, JS ;

NIELSEN, SA ;

LAMB, JD ;

CHRISTENSEN, JJ .

CHEMICAL REVIEWS, 1985, 85 (04) :271-339