Towards f and d electron interactions in amido metal complexes

被引：89

作者：

Kempe, R

Noss, H

Irrgang, T

机构：

[1] Inst Organ Katalyseforsch Rostock, IfOK, D-18055 Rostock, Germany

[2] Carl Von Ossietzky Univ Oldenburg, Fachbereich Chem, D-26111 Oldenburg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 647卷 / 1-2期

关键词：

amido; heterobimetallic; aminopyridinato;

D O I：

10.1016/S0022-328X(01)01475-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A short review of heterobimetallic amido complexes incorporating lanthanides and Group 9 or 10 metals is given. The use of bisaminopyridinato ligands allows the isolation of compounds with very short metal-metal distances. The reaction of bisaminopyridnato 'ate'-complexes with late transition metal chlorides gives rise to such complexes if the ligand transfer from the lanthanide center to the late transition metal can be avoided. (C) 2002 Elsevier Science B.V. All rights reserved.

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页码：12 / 20

页数：9

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