Potential functions for silica and zeolite catalysts based on ab initio calculations .3. A shell model ion pair potential for silica and aluminosilicates

被引:132
作者
Schroder, KP [1 ]
Sauer, J [1 ]
机构
[1] HUMBOLDT UNIV BERLIN,MAX PLANCK SOC,RES UNIT QUANTUM CHEM,D-10117 BERLIN,GERMANY
关键词
D O I
10.1021/jp953405s
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A shell model potential for silica and protonated zeolite catalysts is presented. The potential parameters are fitted exclusively to ab initio data generated by nonempirical quantum chemical calculations on small molecular models made of SiO4 and AlO4 tetrahedra. The Hartree-Fock method has been used with a basis set of double zeta + polarization quality on Si, Al, and H atoms and of valence triple zeta + polarization quality on O atoms. Comparison is made with an ab initio molecular mechanics force field previously derived from the same data and with an empirical parametrization of the shell model potential. The power of the new potential for predicting the crystal structures and the properties is demonstrated for a variety of silica and zeolite structure types. Cell parameters of dense and microporous silica are predicted with a mean error of 1.8%. Compared to earlier potentials, substantial progress is made in predicting dynamical properties. Examples are the phonon dispersion curves of alpha-quartz and the infrared spectrum of zeolite ZSM-5. As a first application to acidic zeolite catalysts the local structures and vibrational frequencies of the different bridging hydroxyl groups in faujasite are calculated. The results do not show the artifacts exhibited by previous potentials.
引用
收藏
页码:11043 / 11049
页数:7
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