Catalytic enantioselective Strecker reactions and analogous syntheses

被引:607
作者
Gröger, H [1 ]
机构
[1] Degussa AG, Project House Biotechnol, D-63457 Hanau, Germany
关键词
D O I
10.1021/cr020038p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Great achievements were made recently in the organocatalytic and metal-catalytic asymmetric hydrocyanation of imines. Several already highly efficient asymmetric methods were currently available for the catalytic enantioselective Strecker reaction. Besides excellent enatioselectivities, the catalysts were particularly noteworthy.
引用
收藏
页码:2795 / 2827
页数:33
相关论文
共 113 条
  • [1] BOLM C, 2000, CATALYTIC ASYMMETRIC, pF399
  • [2] Synthesis and use of enantiomerically pure tert-leucine
    Bommarius, AS
    Schwarm, M
    Stingl, K
    Kottenhahn, M
    Huthmacher, K
    Drauz, K
    [J]. TETRAHEDRON-ASYMMETRY, 1995, 6 (12) : 2851 - 2888
  • [3] BURK MJ, 1998, TRANSITION METALS OR, V2, pF13
  • [4] BURKHART DJ, 2002, 223 AM CHEM SOC NAT
  • [5] Asymmetric Strecker reactions of ketimines catalysed by titanium-based complexes
    Byrne, JJ
    Chavarot, M
    Chavant, PY
    Vallée, Y
    [J]. TETRAHEDRON LETTERS, 2000, 41 (06) : 873 - 876
  • [6] Sc(BINOL)2Li:: a new heterobimetallic catalyst for the asymmetric Strecker reaction
    Chavarot, M
    Byrne, JJ
    Chavant, PY
    Vallée, Y
    [J]. TETRAHEDRON-ASYMMETRY, 2001, 12 (08) : 1147 - 1150
  • [7] Discovery of chiral catalysts through ligand diversity: Ti-catalyzed enantioselective addition of TMSCN to meso epoxides
    Cole, BM
    Shimizu, KD
    Krueger, CA
    Harrity, JPA
    Snapper, ML
    Hoveyda, AH
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (15): : 1668 - 1671
  • [8] Corey EJ, 1998, ANGEW CHEM INT EDIT, V37, P1987, DOI 10.1002/(SICI)1521-3773(19980817)37:15<1986::AID-ANIE1986>3.0.CO
  • [9] 2-Z
  • [10] Enantioselective synthesis of α-amino nitriles from N-benzhydryl imines and HCN with a chiral bicyclic guanidine as catalyst
    Corey, EJ
    Grogan, MJ
    [J]. ORGANIC LETTERS, 1999, 1 (01) : 157 - 160