Unsymmetrical Triphenylamine-Oligothiophene Hybrid Conjugated Systems as Donor Materials for High-Voltage Solution-Processed Organic Solar Cells

被引:100
作者
Ripaud, Emilie [1 ]
Rousseau, Theodulf [1 ]
Leriche, Philippe [1 ]
Roncali, Jean [1 ]
机构
[1] Univ Angers, CNRS Moltech Anjou, Grp Linear Conjugated Syst, F-49045 Angers, France
关键词
INTERNAL CHARGE-TRANSFER; MOLECULE; EFFICIENCY; CORE;
D O I
10.1002/aenm.201100065
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The synthesis of unsymmetrical triphenylamine-oligothiophene hybrid conjugated systems bearing dicy-anovinyl electron acceptor end-groups is presented. When used as molecular donor materials in solution-processed bulk heteroj unction solar cells, these compounds lead to efficient devices with very high open-circuit voltages. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:540 / 545
页数:6
相关论文
共 42 条
[1]   Star-shaped conjugated systems derived from dithiafulvenyl-derivatized triphenylamines as active materials for organic solar cells [J].
Aleveque, Olivier ;
Leriche, Philippe ;
Cocherel, Nicolas ;
Frere, Pierre ;
Cravino, Antonio ;
Roncali, Jean .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2008, 92 (09) :1170-1174
[2]   Light-emitting organic solar cells based on a 3D conjugated system with internal charge transfer [J].
Cravino, Antonio ;
Leriche, Philippe ;
Aleveque, Olivier ;
Roquet, Sophie ;
Roncali, Jean .
ADVANCED MATERIALS, 2006, 18 (22) :3033-+
[3]   Triphenylamine-oligothiophene conjugated systems as organic semiconductors for opto-electronics [J].
Cravino, Antonio ;
Roquet, Sophie ;
Aleveque, Olivier ;
Leriche, Philippe ;
Frere, Pierre ;
Roncali, Jean .
CHEMISTRY OF MATERIALS, 2006, 18 (10) :2584-2590
[4]   Star-shaped perylene-oligothiophene-triphenylamine hybrid systems for photovoltaic applications [J].
Cremer, J ;
Bäuerle, P .
JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (09) :874-884
[5]   Conjugated polymer-based organic solar cells [J].
Guenes, Serap ;
Neugebauer, Helmut ;
Sariciftci, Niyazi Serdar .
CHEMICAL REVIEWS, 2007, 107 (04) :1324-1338
[6]   Improving the efficiency of solution processable organic photovoltaic devices by a star-shaped molecular geometry [J].
He, Chang ;
He, Qingguo ;
Yi, Yuanping ;
Wu, Guanglong ;
Bai, Fenglian ;
Shuai, Zhigang ;
Li, Yongfang .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (34) :4085-4090
[7]   Synthesis and photovoltaic properties of a solution-processable organic molecule containing triphenylamine and DCM moieties [J].
He, Chang ;
He, Qingguo ;
Yang, Xiaodi ;
Wu, Guanglong ;
Yang, Chunhe ;
Bai, Fenglian ;
Shuai, Zhigang ;
Wang, Lingxuan ;
Li, Yongfang .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (24) :8661-8666
[8]   Bulk heterojunction organic solar cells based on merocyanine colorants [J].
Kronenberg, Nils M. ;
Deppisch, Manuela ;
Wuerthner, Frank ;
Lademann, Hans W. A. ;
Deing, Kaja ;
Meerholz, Klaus .
CHEMICAL COMMUNICATIONS, 2008, (48) :6489-6491
[9]   Molecular engineering of the internal charge transfer in thiophene-triphenylamine hybrid π-conjugated systems [J].
Leriche, Philippe ;
Frère, Pierre ;
Cravino, Antonio ;
Aleveque, Olivier ;
Roncali, Jean .
JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (22) :8332-8336
[10]   Solution processable D-A small molecules for bulk-heterojunction solar cells [J].
Li, Yaowen ;
Guo, Qing ;
Li, Zaifang ;
Pei, Jianing ;
Tian, Wenjing .
ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (10) :1427-1436