Synthetic control of framework zinc purinate crystallisation and properties of a large pore, decorated, mixed-linker RHO-type ZIF

被引：31

作者：

Kahr, Juergen ^{[1
]}

Mowat, John P. S. ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Morris, Russell E. ^{[1
]}

Fairen-Jimenez, David ^{[2
]}

Wright, Paul A. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ Edinburgh, Inst Mat & Proc, Sch Engn, Edinburgh EH8 9YL, Midlothian, Scotland

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 53期

基金：

英国工程与自然科学研究理事会;

关键词：

IMIDAZOLATE FRAMEWORKS;

D O I：

10.1039/c2cc32927a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel form of mixed-linker ZIF with the RHO topology is one of four zinc-imidazolate frameworks prepared with purine and 2-nitroimidazole. In this structure the linkers order to give a large pore solid with a high pore volume and an unusual symmetry and linker orientation. It possesses extra-framework zinc imidazolate units decorating the internal surface which can be removed to give high porosity.

引用

页码：6690 / 6692

页数：3