Heck arylation of allylic alcohols in molten salts

被引：95

作者：

Bouquillon, S ^{[1
]}

Ganchegui, B ^{[1
]}

Estrine, B ^{[1
]}

Hénin, F ^{[1
]}

Muzart, J ^{[1
]}

机构：

[1] Univ Reims, CNRS, Fac Sci, UMR React Select & Applicat, F-51687 Reims 2, France

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2001年 / 634卷 / 02期

关键词：

Heck reactions; allylic alcohols; molten ammonium salts; recycling;

D O I：

10.1016/S0022-328X(01)01149-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Heck coupling of ArX (X = I, Br) with allylic alcohols, carried out at 80 - 120 degreesC in molten n-BU4NBr using NaHCO3 as base and PdCl2 as catalyst without extra ligands, leads to the corresponding beta -arylated carbonyl compounds. After extraction of the organic materials with diethyl ether, the ionic layer can be reused directly. (C) 2001 Published by Elsevier Science B.V.

引用

页码：153 / 156

页数：4