Surface modification-based synthesis and microstructural tuning of nanocomposite layers: Monodispersed copper nanoparticles in polyimide resins

被引:81
作者
Akamatsu, K
Ikeda, S
Nawafune, H
Deki, S
机构
[1] Konan Univ, High Technol Res Ctr, Fac Sci & Engn, Kobe, Hyogo 6588501, Japan
[2] Konan Univ, Grad Sch Sci, Kobe, Hyogo 6588501, Japan
[3] Kobe Univ, Fac Engn, Dept Sci & Chem Engn, Kobe, Hyogo 6578501, Japan
关键词
D O I
10.1021/cm034019n
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new approach for the preparation of composite layers of polymide film and copper nanoparticles that relies on surface chemical modification, ion exchange, and hydrogen-induced reduction is described. Annealing in a hydrogen atmosphere after incorporation of Cu2+ ions into the modified polymide surface yields well-formed composite layers of relatively uniform thickness containing monodispersed Cu nanoparticles, accompanied by re-imidization of the modified layers.
引用
收藏
页码:2488 / 2491
页数:4
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