Synthesis of organometallic dendrimers with a backbone composed of platinum-acetylide units

被引：90

作者：

Ohshiro, N ^{[1
]}

Takei, F ^{[1
]}

Onitsuka, K ^{[1
]}

Takahashi, S ^{[1
]}

机构：

[1] Osaka Univ, Inst Sci & Ind Res, Ibaraki, Osaka 5670047, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 569卷 / 1-2期

关键词：

dendrimer; platinum acetylides; polynuclear metal complex;

D O I：

10.1016/S0022-328X(98)00788-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel organometallic dendrimers containing platinum-acetylide units in the main chain have been synthesized up to a henicosanuclear complex (12) using triethynylmesitylene (4) as a bridging ligand. The molecular structure of trinuclear complex (5b), which is a model core of the dendrimer, has been established by an X-ray analysis. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：195 / 202

页数：8

共 30 条

[1] Organoplatinum dendrimers
Achar, S
Vittal, JJ
Puddephatt, RJ
[J]. ORGANOMETALLICS, 1996, 15 (01) : 43 - 50
[2] ORGANOMETALLIC SILICON DENDRIMERS
ALONSO, B
CUADRADO, I
MORAN, M
LOSADA, J
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (22) : 2575 - 2576
[3] CRYSTAL AND MOLECULAR-STRUCTURES OF PARA-PHENYLENE-BIS[ETHYNYLISOTHIOCYANATO-TRANS-BIS(TRIETHYLPHOSPHINE)PLATINUM (II)]
BEHRENS, U
HOFFMANN, K
KOPF, J
MORITZ, J
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 117 (01) : 91 - 98
[4] DENDRIMERS OF NANOMETER-SIZE BASED ON METAL-COMPLEXES - LUMINESCENT AND REDOX-ACTIVE POLYNUCLEAR METAL-COMPLEXES CONTAINING UP TO 22 METAL CENTERS
CAMPAGNA, S
DENTI, G
SERRONI, S
JURIS, A
VENTURI, M
RICEVUTO, V
BALZANI, V
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 1995, 1 (04) : 211 - 221
[5] CARDIN CJ, 1978, J CHEM SOC DALTON, P46, DOI 10.1039/dt9780000046
[6] Ferrocenyl-functionalized poly(propylenimine) dendrimers
Cuadrado, I
Moran, M
Casado, CM
Alonso, B
Lobete, F
Garcia, B
Ibisate, M
Losada, J
[J]. ORGANOMETALLICS, 1996, 15 (25) : 5278 - 5280
[7] GIANT ORGANOMETALLIC NETWORKS DERIVED FROM FERROCENEPOLYSULFIDES
GALLOWAY, CP
RAUCHFUSS, TB
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (09): : 1319 - 1321
[8] HAGIHARA N, 1981, ADV POLYM SCI, V41, P149
[9] ORGANIC-CHEMISTRY - POLYMER SCIENCE BRANCHES OUT
HODGE, P
[J]. NATURE, 1993, 362 (6415) : 18 - 19
[10] Organogermanium dendrimers
Huc, V
Boussaguet, P
Mazerolles, P
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 521 (1-2) : 253 - 260

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