Cascade radical processes leading to polycycle constructions. The total synthesis of spongian-16-one

被引：27

作者：

Pattenden, G

Roberts, L

机构：

[1] Department of Chemistry, Nottingham University

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 24期

关键词：

D O I：

10.1016/0040-4039(96)00740-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A concise total synthesis of the marine sponge metabolite spongian-16-one 1, which features a novel cascade of three consecutive 6-endo-trig radical cyclisations from a polyene acyl radical intermediate as a key step, viz 9 --> 10, is described. (C) 1996 Elsevier Science Ltd

引用

页码：4191 / 4194

页数：4

共 25 条

[21] METABOLITES OF THE MARINE SPONGE DENDRILLA SP [J].