Chemical manipulation of High-TC ferromagnetism in ZnO diluted magnetic semiconductors -: art. no. 147209

被引:424
作者
Kittilstved, KR [1 ]
Norberg, NS
Gamelin, DR
机构
[1] Univ Washington, Dept Chem, Seattle, WA 98195 USA
[2] Univ Washington, Ctr Nanotechnol, Seattle, WA 98195 USA
关键词
D O I
10.1103/PhysRevLett.94.147209
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
We report the use of targeted p- and n-type chemical perturbations to manipulate high-T-C ferromagnetism in Mn2+ZnO and Co2+ZnO in predictable and reproducible ways. We demonstrate a clear correlation between nitrogen and high-T-C ferromagnetism for Mn2+ZnO and an inverse correlation for Co2+ZnO, both as predicted by recent theoretical models. These chemical perturbations reveal rich possibilities for exerting external control over high-T-C spin ordering in diluted magnetic semiconductors.
引用
收藏
页数:4
相关论文
共 32 条
[21]   Magnetic quantum dots:: Synthesis, spectroscopy, and magnetism of CO2+- and Ni2+-doped ZnO nanocrystals [J].
Schwartz, DA ;
Norberg, NS ;
Nguyen, QP ;
Parker, JM ;
Gamelin, DR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (43) :13205-13218
[22]   Quantitative comparisons of dissolved hydrogen density and the electrical and optical properties of ZnO [J].
Seager, CH ;
Myers, SM .
JOURNAL OF APPLIED PHYSICS, 2003, 94 (05) :2888-2894
[23]   Ferromagnetism above room temperature in bulk and transparent thin films of Mn-doped ZnO [J].
Sharma, P ;
Gupta, A ;
Rao, KV ;
Owens, FJ ;
Sharma, R ;
Ahuja, R ;
Guillen, JMO ;
Johansson, B ;
Gehring, GA .
NATURE MATERIALS, 2003, 2 (10) :673-677
[24]   CARRIER-CONCENTRATION INDUCED FERROMAGNETISM IN PBSNMNTE [J].
STORY, T ;
GALAZKA, RR ;
FRANKEL, RB ;
WOLFF, PA .
PHYSICAL REVIEW LETTERS, 1986, 56 (07) :777-779
[25]   INTERSTITIAL ZINC IN ZINC OXIDE [J].
THOMAS, DG .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1957, 3 (3-4) :229-237
[26]   Universal alignment of hydrogen levels in semiconductors, insulators and solutions [J].
Van de Walle, CG ;
Neugebauer, J .
NATURE, 2003, 423 (6940) :626-628
[27]   The kinetics of the radiative and nonradiative processes in nanocrystalline ZnO particles upon photoexcitation [J].
van Dijken, A ;
Meulenkamp, EA ;
Vanmaekelbergh, D ;
Meijerink, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (08) :1715-1723
[28]   Anisotropic ferromagnetism in substituted zinc oxide [J].
Venkatesan, M ;
Fitzgerald, CB ;
Lunney, JG ;
Coey, JMD .
PHYSICAL REVIEW LETTERS, 2004, 93 (17) :177206-1
[29]   Carrier-mediated ferromagnetism in N codoped (Zn,Mn)O (10(1)over-bar-0) thin films [J].
Wang, Q ;
Sun, Q ;
Jena, P ;
Kawazoe, Y .
PHYSICAL REVIEW B, 2004, 70 (05) :052408-1
[30]   Magnetic properties of ZnO-based diluted magnetic semiconductors [J].
Yoon, SW ;
Cho, SB ;
We, SC ;
Yoon, S ;
Suh, BJ ;
Song, HK ;
Shin, YJ .
JOURNAL OF APPLIED PHYSICS, 2003, 93 (10) :7879-7881