Asymmetric benzylic oxidation using a Mn-salen complex as catalyst

被引：94

作者：

Hamachi, K ^{[1
]}

Irie, R ^{[1
]}

Katsuki, T ^{[1
]}

机构：

[1] KYUSHU UNIV 33,FAC SCI,DEPT CHEM,HIGASHI KU,FUKUOKA 81281,JAPAN

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 28期

关键词：

D O I：

10.1016/0040-4039(96)00984-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzylic oxidation using a Mn-salen complex 3 as catalyst and iodosylbenzene as oxidant was found to proceed with moderate enantioselectivity to give the corresponding benzylic alcohol in solvents of high viscosity such as chlorobenzene and fluorobenzene. For example, the oxidation of 1,1-dimethylindane with 3 gave 3-hydroxy-1,1-dimethylindane of 64% ee. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：4979 / 4982

页数：4

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