Enantioselective catalytic hydroamination of alkenes

被引：363

作者：

Roesky, PW

Müller, TE

机构：

[1] Free Univ Berlin, Inst Chem, D-14195 Berlin, Germany

[2] Tech Univ Munich, Inst Tech Chem 2, D-85747 Garching, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 24期

关键词：

asymmetric synthesis; chiral ligands; homogeneous catalysis; hydroamination; iridium; lanthanides;

D O I：

10.1002/anie.200301637

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Catalytically to chirality: Enantioselective catalytic hydroamination (see scheme) is one of the major challenges in synthetic organic and organometallic chemistry and offers a very attractive synthetic pathway to chiral amines. Recent progress made with this reaction is presented.

引用

收藏

页码：2708 / 2710

页数：3

相关论文

共 26 条

[11] Asymmetric catalysis using planar chiral arene chromium complexes [J].

Gibson, SE ;

Ibrahim, H .

CHEMICAL COMMUNICATIONS, 2002, (21) :2465-2473

[12] Highly stereoselective intramolecular hydroamination/cyclization of conjugated aminodienes catalyzed by organolanthanides [J].

Hong, SW ;

Marks, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (27) :7886-7887

[13] Allylic amination [J].

Johannsen, M ;

Jorgensen, KA .

CHEMICAL REVIEWS, 1998, 98 (04) :1689-1708

[14] Palladium-catalyzed intermolecular hydroamination of vinylarenes using arylamines [J].

Kawatsura, M ;

Hartwig, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (39) :9546-9547

[15] Palladium-catalyzed hydroamination of 1,3-dienes:: A colorimetric assay and enantioselective additions [J].

Löber, O ;

Kawatsura, M ;

Hartwig, JF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (18) :4366-4367

[16] Metal-initiated amination of alkenes and alkynes [J].

Muller, TE ;

Beller, M .

CHEMICAL REVIEWS, 1998, 98 (02) :675-703

[17]

MULLER TE, 2002, ENCY CATALYSIS

[18]

Nobis M, 2001, ANGEW CHEM INT EDIT, V40, P3983, DOI 10.1002/1521-3773(20011105)40:21<3983::AID-ANIE3983>3.0.CO

[19]

2-8

[20]

Nobis M., 2001, ANGEW CHEM, V113, P4105