Keggin polyoxometalate with pendant tricyclic, aromatic entity

被引：32

作者：

Han, ZG ^{[1
]}

Zhao, YL ^{[1
]}

Peng, J ^{[1
]}

Ma, HY ^{[1
]}

Liu, Q ^{[1
]}

Wang, EB ^{[1
]}

机构：

[1] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2005年 / 738卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

polyoxometalate; lacunary tungstophosphate; organic capped-structure; 5-phenyl-2-(4-pyridinyl)pyridine; cobalt;

D O I：

10.1016/j.molstruc.2004.07.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A Keggin polyoxometalate with pendant tricyclic, aromatic entity, formulated as (Hpbpy)(5)[PW11O39Co(pbpy)]center dot 2H(2)O (1) (pbpy= 5-phenyl-2-(4-pyridinyl)pyridine), was synthesized and characterized by X-ray single crystal structure analysis and temperature-dependent magnetic susceptibility, which represents an unprecedented organic capped-structure. Crystal data: C96H81N12O41PCOW11, triclinic, P- 1, a = 14.352(3) angstrom, b = 20.467(4) angstrom, c = 21.141(4) angstrom, alpha = 61.30(3)degrees, beta = 75.87(3)degrees, gamma = 88.63(3)degrees, V= 5250.5(18) angstrom(3), Z=2. (c) 2004 Published by Elsevier B.V.

引用

页码：1 / 7

页数：7

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