New diphosphine ligands based on diphenyl ether for the Pd-catalyzed CO/ethene copolymerization

被引：13

作者：

Caporali, M

Müller, C

Staal, BBP

Tooke, DM

Spek, AL

van Leeuwen, PWNM

机构：

[1] Tech Univ Eindhoven, Dept Chem Engn & Chem, NL-5600 MB Eindhoven, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res, Dept Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 27期

关键词：

D O I：

10.1039/b503764f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The catalytic activity and selectivity of palladium(II) complexes of new, flexible bidentate ligands in the CO/ethene copolymerization reaction have been found to change considerably with the steric properties of the ligands.

引用

页码：3478 / 3480

页数：3

共 19 条

[1] Ultrahigh molecular weight alternating propene/ethene/carbon monoxide terpolymers with elastic properties [J].

AbuSurrah, AS ;

Eckert, G ;

Pechhold, W ;

Wilke, W ;

Rieger, B .

MACROMOLECULAR RAPID COMMUNICATIONS, 1996, 17 (08) :559-565

[2]

ASH CE, 1994, J MATER EDUC, V16, P1

[3]

ASH CE, 1995, INT J POLYM MATER, V30, P14

[4] Alternating copolymerization of carbon monoxide and olefins by single-site metal catalysis [J].

Bianchini, C ;

Meli, A .

COORDINATION CHEMISTRY REVIEWS, 2002, 225 (1-2) :35-66

[5] Highly active and selective catalysts for the production of methyl propanoate via the methoxycarbonylation of ethene [J].

Clegg, W ;

Eastham, GR ;

Elsegood, MRJ ;

Tooze, RP ;

Wang, XL ;

Whiston, K .

CHEMICAL COMMUNICATIONS, 1999, (18) :1877-1878

[6] Palladium-catalyzed alternating copolymerization of alkenes and carbon monoxide [J].

Drent, E ;

Budzelaar, PHM .

CHEMICAL REVIEWS, 1996, 96 (02) :663-681

[7]

Gray A, 1998, CHEM BRIT, V34, P44

[8] THE BASICITY OF PHOSPHINES [J].

HENDERSON, WA ;

STREULI, CA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1960, 82 (22) :5791-5794

[9] NEW DIPHOSPHINE LIGANDS BASED ON HETEROCYCLIC AROMATICS INDUCING VERY HIGH REGIOSELECTIVITY IN RHODIUM-CATALYZED HYDROFORMYLATION - EFFECT OF THE BITE ANGLE [J].

KRANENBURG, M ;

VANDERBURGT, YEM ;

KAMER, PCJ ;

VANLEEUWEN, PWNM ;

GOUBITZ, K ;

FRAANJE, J .

ORGANOMETALLICS, 1995, 14 (06) :3081-3089

[10] Methanolysis of acyl-Pd(II) complexes relevant to CO/ethene coupling reactions [J].

Liu, JK ;

Heaton, BT ;

Iggo, JA ;

Whyman, R .

CHEMICAL COMMUNICATIONS, 2004, (11) :1326-1327

← 1 2 →