Transition metals and carbohydrates:: the methyl-4,6-O-benzylidene-2,3-diazo-2,3-dideoxy-α-D-mannopyranoside skeleton as building block for new chiral nitrogen chelates

被引：10

作者：

Borriello, C

De Renzi, A

Fusto, M

Molinaro, A

Ruffo, F

机构：

[1] Univ Naples Federico II, Dipartimento Chim, Complesso Univ Monte S Angelo, I-80126 Naples, Italy

[2] Univ Naples Federico II, Dipartimento Chim Organ & Biochim, Complesso Univ Monte S Angelo, I-80126 Naples, Italy

来源：

CARBOHYDRATE RESEARCH | 2001年 / 331卷 / 02期

关键词：

N; N-ligands; metals; carbohydrate; complexes;

D O I：

10.1016/S0008-6215(01)00022-2

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

This paper describes a straightforward strategy for the synthesis of new nitrogen chelates by employing the chirality of readily available sugars. Thus, diimino and diamino ligands can be attained easily by using the methyl-4,6-O-benzylidene-2,3-diazo-2,3-dideoxy-alpha -D-mannopyranoside skeleton. The coordinating ability of one ligand has also been assessed by preparing a square-planar palladium complex [PdCl2(N,N-chelate)]. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：209 / 212

页数：4

共 19 条

[1] [Pd0(N,N-chelate)(olefin)] complexes containing nitrogen chelates derived from carbohydrates and their use in mild hydrogenation of olefins in water [J].