Novel diphosphite derived from d-gluco-furanose provides high regio- and enantioselectivity in Rh-catalysed hydroformylation of vinyl arenes

被引：64

作者：

Diéguez, M

Pàmies, O

Ruiz, A

Castillón, S

Claver, C

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43005, Spain

[2] Univ Rovira & Virgili, Dept Quim Analit & Organ, Tarragona 43005, Spain

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 17期

关键词：

D O I：

10.1039/b004799f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Both high enantioselectivity (91%) and high regioselectivity (98.8%) are achieved under mild reaction conditions in the Rh-catalysed hydroformylation of vinyl arenes with a new chiral diphosphite ligand derived from the readily available D-(+)-glucose.

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收藏

页码：1607 / 1608

页数：2

相关论文

共 28 条

[1] ASYMMETRIC HYDROFORMYLATION [J].

AGBOSSOU, F ;

CARPENTIER, JF ;

MORTREAUX, A .

CHEMICAL REVIEWS, 1995, 95 (07) :2485-2506

[2]

[Anonymous], 1993, HDB ENANTIOSELECTIVE

[3]

BABIN JE, 1992, Patent No. 911518

[4]

BABIN JE, 1993, Patent No. 03839

[5] PROGRESS IN HYDROFORMYLATION AND CARBONYLATION [J].

BELLER, M ;

CORNILS, B ;

FROHNING, CD ;

KOHLPAINTNER, CW .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 104 (01) :17-85

[6] THE CHIRAL POOL AS A SOURCE OF ENANTIOSELECTIVE CATALYSTS AND AUXILIARIES [J].

BLASER, HU .

CHEMICAL REVIEWS, 1992, 92 (05) :935-952

[7] RHODIUM-CATALYZED ASYMMETRIC HYDROFORMYLATION WITH DIPHOSPHITE LIGANDS BASED ON SUGAR BACKBONES [J].

BUISMAN, GJH ;

MARTIN, ME ;

VOS, EJ ;

KLOOTWIJK, A ;

KAMER, PCJ ;

VANLEEUWEN, PWNM .

TETRAHEDRON-ASYMMETRY, 1995, 6 (03) :719-738

[8] RHODIUM-CATALYZED ASYMMETRIC HYDROFORMYLATION WITH CHIRAL DIPHOSPHITE LIGANDS [J].

BUISMAN, GJH ;

KAMER, PCJ ;

VANLEEUWEN, PWNM .

TETRAHEDRON-ASYMMETRY, 1993, 4 (07) :1625-1634

[9] Chiral cooperativity in diastereomeric diphosphite ligands: Effects on the rhodium-catalyzed enantioselective hydroformylation of styrene [J].

Buisman, GJH ;

vanderVeen, LA ;

Klootwijk, A ;

deLange, WGJ ;

Kamer, PCJ ;

vanLeeuwen, PWNM ;

Vogt, D .

ORGANOMETALLICS, 1997, 16 (13) :2929-2939

[10] Highly regio- and enantio-selective rhodium-catalysed asymmetric hydroformylation without organic solvents [J].

Franciò, G ;

Leitner, W .

CHEMICAL COMMUNICATIONS, 1999, (17) :1663-1664