A new aminophosphine ligand containing axial and planar chiral elements

被引：40

作者：

Widhalm, M

Mereiter, K

Bourghida, M

机构：

[1] Univ Vienna, Inst Organ Chem, A-1090 Vienna, Austria

[2] Vienna Tech Univ, Inst Mineral Kristallog & Strukturchem, A-1040 Vienna, Austria

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 17期

基金：

奥地利科学基金会;

关键词：

D O I：

10.1016/S0957-4166(98)00328-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Synthesis and X-ray structure analyses of the chiral aminophosphine ligand 2a, accessible via diastereoselective ortho-lithiation of aminoferrocene 5, and of its cationic 1,3-diphenyl-pi-allyl palladium complex 6 are reported. Its application in asymmetric allylic alkylation reactions showed asymmetric inductions of up to 71%. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2983 / 2986

页数：4

共 13 条

[1]

[Anonymous], FERROCENES

[2] ASYMMETRIC-SYNTHESIS - ASYMMETRIC CATALYTIC ALLYLATION USING PALLADIUM CHIRAL PHOSPHINE COMPLEXES [J].