A novel series of asymmetric trinuclear M(III) complexes (M = Ti, V, Cr, Mn, Fe, Co) with the [M3O2]6+ core by a deoximation reaction exemplified by the V(III) complex

被引：38

作者：

Chaudhuri, P

Hess, M

Weyhermuller, T

Bill, E

Haupt, HJ

Florke, U

机构：

[1] Max Planck Inst Strahlenchem, D-45413 Mulheim, Germany

[2] Univ Gesamthsch Paderborn, D-33098 Paderborn, Germany

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 1998年 / 1卷 / 02期

关键词：

crystal structures; transition metal complexes; ore-bridged complexes; trinuclear complexes;

D O I：

10.1016/S1387-7003(97)00006-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Compounds with the general formula [Et3NH] [M-3(III)(mu(3)-O) (Salox)(2)(HSalox) (Salmp)], where M(III)=Ti, V, Cr, Mn, Fe or Co, H(2)Salox = salicylaldoxime and H(3)Salmp = 2-(bis(salicylideneamino)methyl)phenol, have been synthesized by a deoximation reaction of salicylaldoxime. (C) 1998 Elsevier Science S.A.

引用

收藏

页码：39 / 42

页数：4

相关论文

共 32 条

[1] BASIC VANADIUM(III) ACETATE - MAGNETIC PROPERTIES OF A TRINUCLEAR CLUSTER COMPLEX [J].

ALLIN, BJ ;

THORNTON, P .

INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1973, 9 (04) :449-452

[2] A triangular Iron(III) complex potentially relevant to iron(III)-binding sites in ferreascidin [J].

Bill, E ;

Krebs, C ;

Winter, M ;

Gerdan, M ;

Trautwein, AX ;

Florke, U ;

Haupt, HJ ;

Chaudhuri, P .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (02) :193-201

[3] Magnetic properties of dodecanuclear mixed valence iron clusters [J].

Caneschi, A ;

Cornia, A ;

Lippard, SJ ;

Papaefthymiou, GC ;

Sessoli, R .

INORGANICA CHIMICA ACTA, 1996, 243 (1-2) :295-304

[4]

CANESCHI A, 1995, ANGEW CHEM, V107, P2862

[5] Structural, spectroscopic, and magnetochemical characterization of the trinuclear vanadium(III) carboxylates [V3O(O(2)CR)(6)L(3)](ClO4) (R=various groups; L=pyridine, 4-picoline, 3,5-lutidine) [J].

Castro, SL ;

Streib, WE ;

Sun, JS ;

Christou, G .

INORGANIC CHEMISTRY, 1996, 35 (15) :4462-4468

[6] Tetranuclear vanadium(III) carboxylate chemistry, and a new example of a metal butterfly complex exhibiting spin frustration: Structure and properties of [V4O2(O(2)CEt)(7)(bpy)(2)](ClO4) [J].

Castro, SL ;

Sun, ZM ;

Bollinger, JC ;

Hendrickson, DN ;

Christou, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1995, (24) :2517-2518

[7] SYNTHESIS, ELECTROCHEMISTRY, AND MAGNETIC AND SPECTROSCOPIC PROPERTIES OF AN EXCHANGE-COUPLED FEIIINIIIFEIII COMPLEX - CRYSTAL-STRUCTURE OF [L2FE2(DMG)3NI](PF6)2.0.5CH3OH (L = 1,4,7-TRIMETHYL-1,4,7-TRIAZACYCLONONANE - DMG = DIMETHYLGLYOXIMATE(2-)) [J].

CHAUDHURI, P ;

WINTER, M ;

DELLAVEDOVA, BPC ;

FLEISCHHAUER, P ;

HAASE, W ;

FLORKE, U ;

HAUPT, HJ .

INORGANIC CHEMISTRY, 1991, 30 (25) :4777-4783

[8] ISOLATION OF A SPIN-FRUSTRATED IMIDAZOLATE-BRIDGED TRINUCLEAR COPPER(II) COMPLEX POTENTIALLY RELEVANT TO THE MULTICOPPER OXIDASES [J].

CHAUDHURI, P ;

KARPENSTEIN, I ;

WINTER, M ;

BUTZLAFF, C ;

BILL, E ;

TRAUTWEIN, AX ;

FLORKE, U ;

HAUPT, HJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (04) :321-322

[9]

CHAUDHURI P, 1991, INORG CHEM, V30, P4292

[10] 4 COMPOUNDS CONTAINING OXO-CENTERED TRIVANADIUM CORES SURROUNDED BY 6 MU,ETA-2-CARBOXYLATO GROUPS [J].

COTTON, FA ;

EXTINE, MW ;

FALVELLO, LR ;

LEWIS, DB ;

LEWIS, GE ;

MURILLO, CA ;

SCHWOTZER, W ;

TOMAS, M ;

TROUP, JM .

INORGANIC CHEMISTRY, 1986, 25 (19) :3505-3512

← 1 2 3 4 →