Analysis on UV-irradiated and 'as grown' silica sample with synchrotron radiation

被引:15
作者
Anedda, A [1 ]
Carbonaro, CM [1 ]
Corpino, R [1 ]
Raga, F [1 ]
机构
[1] Cittadella Univ Monserrato, INFM, Unita Cagliari, I-09042 Monserrato, Italy
关键词
UV-irradiation; photoluminescence; photoluminescence excitation;
D O I
10.1016/S0168-583X(98)00146-3
中图分类号
TH7 [仪器、仪表];
学科分类号
0804 ; 080401 ; 081102 ;
摘要
Optical analysis, including absorption spectra, photoluminescence (PL) and photoluminescence excitation (PLE), has been performed on natural silica sample 'as grown' and UV-irradiated with pulsed KrF excimer laser (5 eV). By synchrotron radiation source we detected the well known alpha and beta emission bands and their excitation spectra at room temperature (RT) and at 10 K (LT). Comparing measurements on irradiated and not-irradiated samples, bleaching of these bands is clearly shown. We hypothesize the observed bleaching of PL bands could be partially correlated to the generation of E' absorption band in UV-irradiated silica sample. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:719 / 725
页数:7
相关论文
共 29 条
[1]   OXYGEN-DEFICIENT CENTERS IN SILICA GLASSES - A REVIEW OF THEIR PROPERTIES AND STRUCTURE [J].
AMOSSOV, AV ;
RYBALTOVSKY, AO .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1994, 179 (pt 3) :75-83
[2]   Experimental evidence of the composite nature of the 3.1 eV luminescence in natural silica [J].
Anedda, A ;
Boscaino, R ;
Cannas, M ;
Corpino, R ;
Gelardi, FM ;
Leone, M .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1996, 116 (1-4) :360-363
[3]   TIME-RESOLVED PHOTOLUMINESCENCE OF ALPHA-CENTERS IN NEUTRON-IRRADIATED SIO2 [J].
ANEDDA, A ;
CONGIU, F ;
RAGA, F ;
CORAZZA, A ;
MARTINI, M ;
SPINOLO, G ;
VEDDA, A .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1994, 91 (1-4) :405-409
[4]   Low temperature time resolved photoluminescence of the 3.1 and 4.2 eV emission bands in Ge-doped silica [J].
Anedda, A ;
Carbonaro, CM ;
Corpino, R ;
Serpi, A .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1997, 216 :19-25
[5]   INHOMOGENEOUS NATURE OF UV ABSORPTION-BANDS OF BULK AND SURFACE OXYGEN-DEFICIENT CENTERS IN SILICA GLASSES [J].
BAGRATASHVILI, VN ;
TSYPINA, SI ;
RADTSIG, VA ;
RYBALTOVSKII, AO ;
CHERNOV, PV ;
ALIMPIEV, SS ;
SIMANOVSKII, YO .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1995, 180 (2-3) :221-229
[6]   ESR and PL centers induced by gamma rays in silica [J].
Boscaino, R ;
Cannas, M ;
Gelardi, FM ;
Leone, M .
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1996, 116 (1-4) :373-377
[7]   Spectral and kinetic properties of the 4.4-eV photoluminescence band in alpha-SiO2: Effects of gamma irradiation [J].
Boscaino, R ;
Cannas, M ;
Gelardi, FM ;
Leone, M .
PHYSICAL REVIEW B, 1996, 54 (09) :6194-6199
[8]   Ab initio study of oxygen vacancies in alpha-quartz [J].
Carbonaro, CM ;
Fiorentini, V ;
Massidda, S .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1997, 221 (01) :89-96
[9]   THE DOUBLE NATURE OF THE 3.1 EV EMISSION IN SILICA AND IN GE-DOPED SILICA [J].
CORAZZA, A ;
CRIVELLI, B ;
MARTINI, M ;
SPINOLO, G .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1995, 7 (33) :6739-6745
[10]   Photoinduced conversion of optically active defects in germanium-doped silica [J].
Crivelli, B ;
Martini, M ;
Meinardi, F ;
Paleari, A ;
Spinolo, G .
PHYSICAL REVIEW B, 1996, 54 (23) :16637-16640