Atmospheric pressure microwave assisted heterogeneous catalytic reactions

被引：37

作者：

Chemat-Djenni, Zoubida ^{[1
]}

Hamada, Boudjema

Chemat, Farid

机构：

[1] Univ MHamed Bouguerra, Fac Hydrocarbures & Chim, Lab Synthese Petrochim, Boumerdes 35000, Algeria

[2] Univ Saad Dahlab, Fac Med, Blida 09000, Algeria

[3] UAPV, INRA, UMR A408, F-84029 Avignon, France

来源：

MOLECULES | 2007年 / 12卷 / 07期

关键词：

microwaves; heterogeneous reactions; isomerisation; xylene;

D O I：

10.3390/12071399

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The purpose of the study was to investigate microwave selective heating phenomena and their impact on heterogeneous chemical reactions. We also present a tool which will help microwave chemists to answer to such questions as "My reaction yields 90% after 7 days at reflux; is it possible to obtain the same yield after a few minutes under microwaves?" and to have an approximation of their reactions when conducted under microwaves with different heterogeneous procedures. This model predicting reaction kinetics and yields under microwave heating is based on the Arrhenius equation, in agreement with experimental data and procedures.

引用

页码：1399 / 1409

页数：11

共 11 条

[1]

Bernard J., 2001, Sci. Vie, V214, P68

[2]

Chemat F, 1998, J MICROWAVE POWER EE, V33, P88

[3] Towards the rehabilitation of the Mathews' 'dry' hydrolysis reaction using microwave technology [J].