The development of enantioselective rhodium-catalysed hydroboration of olefins

被引：299

作者：

Carroll, AM ^{[1
]}

O'Sullivan, TP ^{[1
]}

Guiry, PJ ^{[1
]}

机构：

[1] Univ Coll Dublin, Ctr Synth & Chem Biol, Conway Inst Biomol & Biomed Res, Dept Chem, Dublin 4, Ireland

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2005年 / 347卷 / 05期

关键词：

asymmetric catalysis; hydroboration; P; N chiral ligands; P chiral ligands; mechanistic studies; rhodium;

D O I：

10.1002/adsc.200404232

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Rhodium-catalysed enantioselective hydroboration of olefins is a valuable synthetic transformation, typically employing a chiral catalyst and an achiral borane source. The pertinent chemo-, regio- and enantioselectivity issues of this reaction are discussed. However, the main emphasis of this review is on the evolution of catalytic asymmetric hydroboration. This has primarily relied upon the development and application of chiral bidentate PP and P,N ligands which have exhibited varying degrees of success in this transformation.

引用

页码：609 / 631

页数：23

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