Ruthenium-catalyzed asymmetric hydrosilylation of ketones and imine

被引：169

作者：

Nishibayashi, Y

Takei, I

Uemura, S ^{[1
]}

Hidai, M

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan

[2] Univ Tokyo, Dept Chem & Biotechnol, Grad Sch Engn, Tokyo 1138656, Japan

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 16期

关键词：

D O I：

10.1021/om980399o

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ruthenium complexes with (oxazolinylferrocenyl)phosphines, RuCl2(PPh3)((oxazolinylferrocenyl)-phosphine), have been prepared and characterized by spectroscopy. these ruthenium complexes are very effective catalysts for asymmetric hydrosilylation of not only ketones but also an imine to give the corresponding sec-alcohols (up to 97% ee) and a sec-amine (88% ee) after acid hydrolysis, respectively.

引用

收藏

页码：3420 / 3422

页数：3

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