Oscillating Langmuir-Hinshelwood mechanisms

被引：59

作者：

Eiswirth, M

Burger, J

Strasser, P

Ertl, G

机构：

[1] Fritz-Haber-Institut der Max-Planck-Gesellschaft, D-14195 Berlin

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 49期

关键词：

D O I：

10.1021/jp961688y

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Sufficient and necessary conditions for the occurrence of a Hopf bifurcation in chemical reaction mechanisms are presented using the formalism of stoichiometric networks. The conditions are applied to determine the mechanistic basis of chemical oscillations in isothermal surface reactions. Realistic examples are given for the different oscillatory mechanisms.

引用

页码：19118 / 19123

页数：6

共 41 条

[1]

BAR M, 1992, J CHEM PHYS, V96, P8595, DOI 10.1063/1.462312

[2] MATHEMATICAL-MODELING OF KINETIC OSCILLATIONS IN THE CATALYTIC CO OXIDATION ON PD(110) - THE SUBSURFACE OXYGEN MODEL [J].