Asymmetric cyanosilylation of aldehydes catalyzed by novel organo-catalysts

被引：92

作者：

Wen, YH ^{[1
]}

Huang, X ^{[1
]}

Huang, JL ^{[1
]}

Xiong, Y ^{[1
]}

Qin, B ^{[1
]}

Feng, XM ^{[1
]}

机构：

[1] Sichuan Univ, Coll Chem, Key Lab Green Chem & Technol, Minist Educ, Chengdu 610064, Peoples R China

来源：

SYNLETT | 2005年 / 16期

关键词：

proline-based N; N; '-dioxide; aldehydes; organocalalyst; cyallosilylation; enantioselectivity;

D O I：

10.1055/s-2005-872692

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel proline-based N,N'-dioxide, which is easily prepared from inexpensive chemicals, serves as an effective catalyst for enantioselective cyanosilylation of aldehydes ill Lip to 73% ee.

引用

页码：2445 / 2448

页数：4

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