N-Metalated imines by reaction of 1,1-diethoxybut-2-ene with aromatic nitriles, as useful intermediates for the synthesis of substituted pyrimidines and cyclopentenones

被引：19

作者：

Blangetti, Marco ^{[1
]}

Deagostino, Annamaria ^{[1
]}

Prandi, Cristina ^{[1
]}

Zavattaro, Chiara ^{[1
,2
]}

Venturello, Paolo ^{[1
]}

机构：

[1] Univ Turin, Dipartimento Chim Gen & Chim Organ, I-10125 Turin, Italy

[2] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 14期

关键词：

D O I：

10.1039/b719462e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new approach to the synthesis of pyrimidines and cyclopentenones is described. The method exploits the reactivity of alpha,beta-unsaturated acetals with aromatic nitriles in the presence of the Schlosser's superbase LIC-KOR.

引用

页码：1689 / 1691

页数：3

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