Processing of CdTe thin films by the stacked elemental layer method: compound formation and physical properties

被引:3
作者
Cruz, LR
Matson, R
de Avillez, RR
机构
[1] Inst Mil Engn, Dept Engn Macan & Mat, BR-22290270 Rio De Janeiro, Brazil
[2] Natl Renewable Energy Lab, Golden, CO 80401 USA
[3] Pontificia Univ Catolica Rio de Janeiro, BR-22543900 Rio De Janeiro, Brazil
关键词
SEL technique; CdTe; physical properties; characterization; CdCl2; treatment; thin film reaction;
D O I
10.1016/S0167-577X(00)00213-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Cadmium telluride (CdTe) thin films have been deposited using the stacked elemental layer (SEL) technique. This process consists of sequentially depositing tellurium and cadmium layers and then annealing the stacks in order to synthesize the compound. The films were characterized using X-ray diffraction (XRD), optical transmittance and reflectance, scanning electron microscopy (SEM) and atomic force microscopy (AFM). The evolution of the thin film reaction and compound formation were studied using X-ray data. The results show that the growth is diffusion-controlled and the activation energy is (82 +/- 2) kJ/mol. The effect of the conventional post-synthesis CdCl2 heat treatment on the physical properties of the films produced is also reported. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:63 / 70
页数:8
相关论文
共 13 条
[1]  
Basol B. M., 1992, International Journal of Solar Energy, V12, P25, DOI 10.1080/01425919208909748
[2]  
Bhatti M. T., 1992, International Journal of Solar Energy, V12, P171, DOI 10.1080/01425919208909760
[3]  
CARTER MJ, 1987, P 19 IEEE PHOT SPEC, P1275
[4]  
Chu T. L., 1993, Progress in Photovoltaics: Research and Applications, V1, P31, DOI 10.1002/pip.4670010105
[5]   The influence of post-deposition treatment on the physical properties of CdTe films deposited by stacked elemental layer processing [J].
Cruz, LR ;
Kazmerski, LL ;
Moutinho, HR ;
Hasoon, F ;
Dhere, RG ;
de Avillez, R .
THIN SOLID FILMS, 1999, 350 (1-2) :44-48
[6]   GROWTH-KINETICS OF PLANAR BINARY DIFFUSION COUPLES - THIN-FILM CASE VERSUS BULK CASES [J].
GOSELE, U ;
TU, KN .
JOURNAL OF APPLIED PHYSICS, 1982, 53 (04) :3252-3260
[7]  
JAMES RW, 1950, OPTICAL PRINCIPLES D, P54
[8]   SOME ASPECTS OF THE GROWTH OF DIFFUSION LAYERS IN BINARY SYSTEMS [J].
KIDSON, GV .
JOURNAL OF NUCLEAR MATERIALS, 1961, 3 (01) :21-29
[9]   ANALYSIS OF POST DEPOSITION PROCESSING FOR CDTE/CDS THIN-FILM SOLAR-CELLS [J].
MCCANDLESS, BE ;
BIRKMIRE, RW .
SOLAR CELLS, 1991, 31 (06) :527-535
[10]   THIN-FILMS OF CDTE PRODUCED USING STACKED ELEMENTAL LAYER PROCESSING FOR USE IN CDTE CDS SOLAR-CELLS [J].
MILES, RW ;
BHATTI, MT ;
HYNES, KM ;
BAUMANN, AE ;
HILL, R .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 1993, 16 (1-3) :250-256