Capture of NiII, CuI and ZnII by thiolate sulfurs of an N2S2Ni complex:: A role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site

被引:49
作者
Golden, ML [1 ]
Rampersad, MV [1 ]
Reibenspies, JH [1 ]
Darensbourg, MY [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
关键词
D O I
10.1039/b304884p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The metal binding affinity of an (N2S2) Ni bridging metallothiolate ligand (Zn2+ < Ni2+ < Cu+) gives precedent for the observed heterogeneity in ACS/CODH.
引用
收藏
页码:1824 / 1825
页数:2
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