Capture of NiII, CuI and ZnII by thiolate sulfurs of an N2S2Ni complex:: A role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site

被引：49

作者：

Golden, ML ^{[1
]}

Rampersad, MV ^{[1
]}

Reibenspies, JH ^{[1
]}

Darensbourg, MY ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 15期

关键词：

D O I：

10.1039/b304884p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The metal binding affinity of an (N2S2) Ni bridging metallothiolate ligand (Zn2+ < Ni2+ < Cu+) gives precedent for the observed heterogeneity in ACS/CODH.

引用

页码：1824 / 1825

页数：2

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