Supramolecular catalytic systems based on calixarenes and cyclodextrins

被引：14

作者：

Karakhanov, EE ^{[1
]}

Maksimov, AL ^{[1
]}

Runova, EA ^{[1
]}

Kardasheva, YS ^{[1
]}

Terenina, MV ^{[1
]}

Buchneva, TS ^{[1
]}

Guchkova, AY ^{[1
]}

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119997, Russia

来源：

MACROMOLECULAR SYMPOSIA | 2003年 / 204卷

关键词：

calixarene; cyclodextrin; hydroformylation; molecular recognition; two-phase catalysis; Wacker-oxidation;

D O I：

10.1002/masy.200351414

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A number of supramolecular metal complex catalitic system based on cyclodextrins and calixarenes have been developed. Particular attention has been given to design of new metal complexes with molecular recognition abilities. Data on application catalytic systems based on receptor molecules capable to formation of inclusion "host-guest" complexes in hydroformylation and Wacker-oxidation are given. Influence of different factors on activity, stability, selectivity of metal complex supramolecular catalytic systems is discussed.

引用

页码：159 / 173

页数：15

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