On the second-order nonlinear optical structure - Property relationships of metal chromophores

被引:65
作者
Base, K
Tierney, MT
Fort, A
Muller, J
Grinstaff, MW [1 ]
机构
[1] Duke Univ, Dept Chem, PM Gross Chem Lab, Durham, NC 27708 USA
[2] CNRS, Inst Phys & Chim Mat Strasbourg, F-67037 Strasbourg, France
关键词
D O I
10.1021/ic980872q
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and solvent-dependent second-order polarizability, beta, responses of three new platinum(II) chromophores are reported. A strong correlation between the metal chromophore electronic structure and the second-order polarizability is observed that substantiates the use of the two-state model to design, optimize, and study new NLO chromophores.
引用
收藏
页码:287 / 289
页数:3
相关论文
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