Pore topology control of three-dimensional large pore cubic silica mesophases

被引：48

作者：

Yang, CM ^{[1
]}

Schmidt, W

Kleitz, F

机构：

[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan

[2] Max Planck Inst Kohlenforsch, D-45470 Mulheim An Der Ruhr, Germany

[3] Univ Laval, Dept Chem, Ste Foy, PQ G1K 7P4, Canada

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2005年 / 15卷 / 48期

关键词：

D O I：

10.1039/b513833g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Facile synthetic modulation of the pore shape and pore entrance of large pore cubic silica mesophases with fcc and bcc three-dimensional structures was achieved by applying post-synthesis treatment with sulfuric acid.

引用

页码：5112 / 5114

页数：3

共 17 条

[1] Facile synthesis of high quality mesoporous SBA-15 with enhanced control of the porous network connectivity and wall thickness [J].

Choi, M ;

Heo, W ;

Kleitz, F ;

Ryoo, R .

CHEMICAL COMMUNICATIONS, 2003, (12) :1340-1341

[2] Tailoring the pore structure of SBA-16 silica molecular sieve through the use of copolymer blends and control of synthesis temperature and time [J].

Kim, TW ;

Ryoo, R ;

Kruk, M ;

Gierszal, KP ;

Jaroniec, M ;

Kamiya, S ;

Terasaki, O .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (31) :11480-11489

[3] Calcination behavior of different surfactant-templated mesostructured silica materials [J].

Kleitz, F ;

Schmidt, W ;

Schüth, F .

MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 65 (01) :1-29

[4] Transformation of highly ordered large pore silica mesophases (Fm3m, Im3m and p6mm) in a ternary triblock copolymer-butanol-water system [J].

Kleitz, F ;

Solovyov, LA ;

Anilkumar, GM ;

Choi, SH ;

Ryoo, R .

CHEMICAL COMMUNICATIONS, 2004, (13) :1536-1537

[5] Large cage face-centered-cubic Fm3m mesoporous silica:: Synthesis and structure [J].

Kleitz, F ;

Liu, DN ;

Anilkumar, GM ;

Park, IS ;

Solovyov, LA ;

Shmakov, AN ;

Ryoo, R .

JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (51) :14296-14300

[6] Synthesis of FDU-1 silica with narrow pore size distribution and tailorable pore entrance size in the presence of sodium chloride [J].

Kruk, M ;

Celer, EB ;

Matos, JR ;

Pikus, S ;

Jaroniec, M .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (09) :3838-3843

[7] Ordered mesoporous silica with large cage-like pores: Structural identification and pore connectivity design by controlling the synthesis temperature and time [J].

Matos, JR ;

Kruk, M ;

Mercuri, LP ;

Jaroniec, M ;

Zhao, L ;

Kamiyama, T ;

Terasaki, O ;

Pinnavaia, TJ ;

Liu, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (03) :821-829

[8] Characterization of micro- and mesoporosity in SBA-15 materials from adsorption data by the NLDFT method [J].

Ravikovitch, PI ;

Neimark, AV .

JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (29) :6817-6823

[9] Density functional theory of adsorption in spherical cavities and pore size characterization of templated nanoporous silicas with cubic and three-dimensional hexagonal structures [J].

Ravikovitch, PI ;

Neimark, AV .

LANGMUIR, 2002, 18 (05) :1550-1560

[10] Block-copolymer-templated ordered mesoporous silica: Array of uniform mesopores or mesopore-micropore network? [J].

Ryoo, R ;

Ko, CH ;

Kruk, M ;

Antochshuk, V ;

Jaroniec, M .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (48) :11465-11471

← 1 2 →