Optimization of alkyl ester production from grease using a phyllosilicate sol-gel immobilized lipase

被引:21
作者
Hsu, AF [1 ]
Jones, KC [1 ]
Foglia, TA [1 ]
Marmer, WN [1 ]
机构
[1] USDA ARS, Eastern Reg Res Ctr, Wyndmoor, PA 19038 USA
关键词
alkyl esters; biodiesel; branched esters; immobilized lipase; recycled grease;
D O I
10.1023/A:1026094318940
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Simple alkyl ester derivatives of restaurant grease were prepared using a lipase from Pseudomonoas cepacia immobilized within a phyllosilicate sol-gel matrix as biocatalyst. Alcoholysis reactions of grease were carried out in solvent-free media using a one-step addition of alcohol to the reaction mixture. The immobilized lipase was active from 40 to 70 degreesC. Ester yields (60-97%) were highest when using a ratio of reactants of 2 mmol grease to 8 mmol alcohol and the biocatalyst was 10% (w/w) of grease in the presence of molecular sieves.
引用
收藏
页码:1713 / 1716
页数:4
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