Nonlinear magnetooptical effects caused by piezoelectric ferromagnetism in F43m-type Prussian blue analogues

被引：110

作者：

Nuida, T

Matsuda, T

Tokoro, H

Sakurai, S

Hashimoto, K

Ohkoshi, S

机构：

[1] Univ Tokyo, Sch Engn, Dept Appl Chem, Bunkyo Ku, Tokyo 1138656, Japan

[2] JST, PRESTO, Kawaguchi, Saitama 3320012, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 33期

关键词：

D O I：

10.1021/ja0535662

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The second harmonic generation (SHG) and magnetization-induced SHG (MSHG) of AMA[MB(CN)6]-type (F43m) Prussian blue analogues (i.e., CsCo[Cr(CN)6]·0.5H2O and RbMn[Fe(CN)6]) were observed. A large interaction between the nonlinear optical response and magnetic spins was observed in CsCo[Cr(CN)6]·0.5H2O. These observations of SHG and MSHG imply that AMA[MB(CN)6]-type Prussian blue analogues are piezoelectric above the Curie temperature (TC) and piezoelectric ferromagnet below TC. Copyright © 2005 American Chemical Society.

引用

页码：11604 / 11605

页数：2

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