Nano-cluster-enhanced high-performance perfluoro-polymer electrets for energy harvesting

被引:78
作者
Kashiwagi, Kimiaki [1 ]
Okano, Kuniko [1 ]
Miyajima, Tatsuya [1 ]
Sera, Yoichi [1 ]
Tanabe, Noriko [1 ]
Morizawa, Yoshitomi [1 ]
Suzuki, Yuji [2 ]
机构
[1] Asahi Glass Co Ltd, Res Ctr, Kanagawa Ku, Yokohama, Kanagawa 2218757, Japan
[2] Univ Tokyo, Dept Mech Engn, Bunkyo Ku, Tokyo 1138656, Japan
关键词
STABILITY; FILMS;
D O I
10.1088/0960-1317/21/12/125016
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Development of high-performance electret materials is required to obtain a large power output of the electrostatic vibration-driven energy harvesters. In this study, by introducing aminosilane derivatives into CYTOP-based perfluorinated polymer film, we have successfully formed nano-clusters containing the organic siloxanes in the polymer electrets. Using small-angle x-ray scattering, tapping mode AFM and SEM analysis, the existence of such nano-clusters has been directly observed in the CYTOP film. It is suggested that the observed nano-clusters serve as the charge trap site and enhance the surface charge density and the thermal stability of the trapped charges. As a polymer electret, an extremely high surface charge potential of -1.6 kV with the 15 mu m thick film has been obtained under the optimum condition of corona charging.
引用
收藏
页数:8
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