Highly Efficient Activation of Molecular Oxygen with Nanoporous Metalloporphyrin Frameworks in Heterogeneous Systems

被引：158

作者：

Chen, Long ^{[1
]}

Yang, Yong ^{[1
]}

Guo, Zhaoqi ^{[1
]}

Jiang, Donglin ^{[1
,2
]}

机构：

[1] Natl Inst Nat Sci, Inst Mol Sci, Dept Mat Mol Sci, Okazaki, Aichi 4448787, Japan

[2] Japan Sci & Technol Agcy JST, Chiyoda Ku, Tokyo 1020075, Japan

来源：

ADVANCED MATERIALS | 2011年 / 23卷 / 28期

基金：

日本科学技术振兴机构;

关键词：

CONJUGATED MICROPOROUS POLYMER; SURFACE-AREA; NETWORKS; CATALYSTS; CARBON; PHTHALOCYANINE; OXIDATIONS;

D O I：

10.1002/adma.201100974

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nanoporous metalloporphyrin framework exhibits high activity in the activation of molecular oxygen and excellent catalytic activity in the aerobic epoxidation of olefins, with high conversion, outstanding selectivity, and broad substrate applicability. The porous framework is reusable and allows large-scale transformation. These catalytic features are correlated with the structural characteristics of the porous framework and mark a breakthrough for this classic reaction.

引用

页码：3149 / +

页数：7

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