Reactions of ruthenium(II) tris(pyrazolyl)borate and tris(pyrazolyl)methane complexes with diphenylvinylphosphine and 3,4-dimethyl-1-phenylphosphole

被引：21

作者：

Wilson, DC ^{[1
]}

Nelson, JH ^{[1
]}

机构：

[1] Univ Nevada, Dept Chem 216, Reno, NV 89557 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 682卷 / 1-2期

关键词：

ruthenium; tris(pyrazolyl)borate; tris(pyrazolyl)methane; phosphaallyl; 4+2] Diels-Alder cycloaddition;

D O I：

10.1016/j.jorganchem.2003.07.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several new ruthenium(II) tris(pyrazolyl)borate and tris(pyrazolyl)methane complexes containing diphenylvinylphosphine (DPVP), 3,4-dimethyl-1-phenylphosphole (DMPP) and 1,2-bis (diphenylphosphino) ethane (dppe), namely: (Tp)Ru (DPVP) (CH3CN)Cl; (Tp)Ru (DPVP)(2)CI; (Tp)Ru (DPVP) (DMPP) [4 + 2]Cl; [(Tp)Ru (DPVP)(2) (CH3CN)]PF6; (Tp)Ru (DMPP)(2) [4 + 2]Cl; [(Tpm)Ru (DPVP)(2) CI]PF6; [(Tpm)Ru(dppe)CI]PF6; [(Tpm)Ru(DMPP)(2) [4 + 2]CI]PF6 and [(Tp)Ru (dppe) (Me2CO)]PF6 have been prepared, characterized and their reaction chemistry studied. Characterization includes infrared spectroscopy, H-1-, C-13{H-1}- and P-31{H-1}-NMR spectroscopy and in several cases X-ray crystallography. (C) 2003 Elsevier B.V. All rights reserved.

引用

页码：272 / 289

页数：18

共 80 条

[1] RUTHENATETRABORANES - SYNTHESIS OF [RU(B3H8)(PPH3)(HB(PZ)3)] AND CRYSTAL-STRUCTURE OF [RUCL(PPH3)2(HB(PZ)3)] (PZ = PYRAZOL-1-YL) [J].