Oxiranyllithium based synthesis of α-keto-2-oxazolines

被引：18

作者：

Capriati, V ^{[1
]}

Florio, S ^{[1
]}

Luisi, R ^{[1
]}

Russo, V ^{[1
]}

Salomone, A ^{[1
]}

机构：

[1] Univ Bari, CNR, Ctr Studio Metodol Innovat Sintesi Organ, Dipartimento Farmacochim, I-70125 Bari, Italy

来源：

TETRAHEDRON LETTERS | 2000年 / 41卷 / 45期

关键词：

oxazolinyl oxiranes; oxiranyllithiums; alpha-keto-2-oxazolines; oxirane-ketone rearrangement;

D O I：

10.1016/S0040-4039(00)01558-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

alpha -Keto-2-oxazolines 5a-j have been efficiently prepared by lithiation [sec-(or n-)BuLi/TMEDA, Et2O, -100 degreesC] and rearrangement of oxiranyl oxazolines 2a-j. (C) 2000 Published by Elsevier Science Ltd.

引用

页码：8835 / 8838

页数：4

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