Secondary organic aerosol formation by irradiation of 1,3,5-trimethylbenzene-NOx-H2O in a new reaction chamber for atmospheric chemistry and physics

被引：144

作者：

Paulsen, D

Dommen, J

Kalberer, M

Prévôt, ASH

Richter, R

Sax, M

Steinbacher, M

Weingartner, E

Baltensperger, U ^{[1
]}

机构：

[1] Paul Scherrer Inst, Lab Atmospher Chem, CH-5232 Villigen, Switzerland

[2] ETH, Dept Chem & Appl Biosci, CH-8093 Zurich, Switzerland

来源：

ENVIRONMENTAL SCIENCE & TECHNOLOGY | 2005年 / 39卷 / 08期

关键词：

D O I：

10.1021/es0489137

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

A new environmental reaction smog chamber was built to simulate particle formation and growth similar to that expected in the atmosphere. The organic material is formed from nucleation of photooxidized organic compounds. The chamber is a 27 m(3) fluorinated ethylene propylene (FEP) bag suspended in a temperature-controlled enclosure. Four xenon arc lamps (16 kW total) are used to irradiate primary gas components for experiments lasting up to 24 h. Experiments using irradiations of 1,3,5-trimethylbenzene - NOx-H2O at similar input concentrations without seed particles were used to determine particle number and volume concentration wall loss rates of 0.209 +/- 0.018 and 0.139 +/- 0.070 h(-1), respectively. The particle formation was compared with and without propene.

引用

收藏

页码：2668 / 2678

页数：11

相关论文

共 48 条

[21] Heterogeneous atmospheric aerosol production by acid-catalyzed particle-phase reactions [J].

Jang, MS ;

Czoschke, NM ;

Lee, S ;

Kamens, RM .

SCIENCE, 2002, 298 (5594) :814-817

[22] Identification of polymers as major components of atmospheric organic aerosols [J].

Kalberer, M ;

Paulsen, D ;

Sax, M ;

Steinbacher, M ;

Dommen, J ;

Prevot, ASH ;

Fisseha, R ;

Weingartner, E ;

Frankevich, V ;

Zenobi, R ;

Baltensperger, U .

SCIENCE, 2004, 303 (5664) :1659-1662

[23] Kinetic Study of the OH-isoprene and O3-isoprene reaction in the atmosphere simulation chamber, SAPHIR [J].

Karl, M ;

Brauers, T ;

Dorn, HP ;

Holland, F ;

Komenda, M ;

Poppe, D ;

Rohrer, F ;

Rupp, L ;

Schaub, A ;

Wahner, A .

GEOPHYSICAL RESEARCH LETTERS, 2004, 31 (05) :1-4

[24] CHARACTERIZATION OF FLUOROCARBON-FILM BAGS AS SMOG CHAMBERS [J].

KELLY, NA .

ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1982, 16 (11) :763-770

[25] Secondary organic aerosol formation from the oxidation of aromatic hydrocarbons in the presence of dry submicron ammonium sulfate aerosol [J].

Kleindienst, TE ;

Smith, DF ;

Li, W ;

Edney, EO ;

Driscoll, DJ ;

Speer, RE ;

Weathers, WS .

ATMOSPHERIC ENVIRONMENT, 1999, 33 (22) :3669-3681

[26] On-line monitoring of volatile organic compounds at pptv levels by means of proton-transfer-reaction mass spectrometry (PTR-MS) - Medical applications, food control and environmental research [J].

Lindinger, W ;

Hansel, A ;

Jordan, A .

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1998, 173 (03) :191-241

[27]

LINDINGER W, 1986, GASEOUS ION CHEM MAS, P237

[28] AEROSOL MOBILITY CHROMATOGRAPH - NEW DETECTOR FOR SULFURIC-ACID AEROSOLS [J].

LIU, BYH ;

PUI, DYH ;

WHITBY, KT ;

KITTELSON, DB ;

KOUSAKA, Y ;

MCKENZIE, RL .

ATMOSPHERIC ENVIRONMENT, 1978, 12 (1-3) :99-104

[29] A new cascade impactor for aerosol sampling with subsequent PIXE analysis [J].

Maenhaut, W ;

Hillamo, R ;

Makela, T ;

Jaffrezo, JL ;

Bergin, MH ;

Davidson, CI .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1996, 109 :482-487

[30] ON THE SENSITIVITY OF PARTICLE-SIZE TO RELATIVE-HUMIDITY FOR LOS-ANGELES AEROSOLS [J].

MCMURRY, PH ;

STOLZENBURG, MR .

ATMOSPHERIC ENVIRONMENT, 1989, 23 (02) :497-507

← 1 2 3 4 5 →