Novel bimetallic thiocarboxylate compounds as single-source precursors to binary and ternary metal sulfide materials

被引：63

作者：

Deivaraj, TC

Park, JH

Afzaal, M

O'Brien, P

Vittal, JJ

机构：

[1] Univ Manchester, Manchester Mat Sci Ctr, Manchester M13 9PL, Lancs, England

[2] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

[3] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore

来源：

CHEMISTRY OF MATERIALS | 2003年 / 15卷 / 12期

关键词：

D O I：

10.1021/cm031027v

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The binuclear compounds [(Ph3P)CUM(SC{O}Ph)(4)] (M = Ga (1) or In (2)), [(Ph3P)(2) AgGa(SC{O}Ph)(4)] (3), [(Ph3P)(2) AgIn(SC{O}R)(4)1] (R = Me (4) or Ph (5)) have been synthesized and characterized. The solid-state structures of compounds 1 - 3 have been determined by X-ray crystallography. Thermogravimetry and pyrolysis studies revealed that these compounds decompose to give the corresponding ternary metal sulfide materials. However, using the aerosol-assisted chemical vapor deposition (AACVD) method, In2S3 thin films were obtained from 2 and AgIn5S8 thin films were obtained from compounds 4 and 5.

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页码：2383 / 2391

页数：9

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