Synthesis and characterization of the first liquid single-source precursors for the deposition of ternary chalcopyrite (CuInS2) thin film materials

被引：66

作者：

Banger, KK

Cowen, J

Hepp, AF ^{[1
]}

机构：

[1] NASA, Glenn Res Ctr, Photovolta & Space Environm Branch, Cleveland, OH 44135 USA

[2] Ohio Aerosp Inst, Cleveland, OH 44142 USA

[3] Cleveland State Univ, Dept Chem, Cleveland, OH 44115 USA

来源：

CHEMISTRY OF MATERIALS | 2001年 / 13卷 / 11期

关键词：

D O I：

10.1021/cm010507o

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Molecular engineering of ternary single-source precursors based on the [{PBu3}(2)Cu(SR')(2)In-(SR')(2)] architecture have afforded the first liquid CIS ternary single-source precursors (when R = Et, n-Pr), which are suitable for low-temperature deposition (< 350 degreesC). Thermogravimetric analyses (TGA) and modulated DSC confirm their liquid phase and reduced stability. X-ray diffraction studies, EDS, and SEM support the formation of the single-phase chalcopyrite CuInS2 at low temperatures.

引用

页码：3827 / +

页数：4

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