C 1s photoemission spectrum in graphite(0001)

被引:19
作者
Lizzit, S. [1 ]
Petaccia, L. [1 ]
Goldoni, A. [1 ]
Larciprete, R. [1 ,2 ]
Hofmann, Ph. [3 ,4 ]
Zampieri, G. [5 ,6 ]
机构
[1] Sincrotrone Trieste SCpA, I-34012 Trieste, Italy
[2] CNR, Inst Complex Syst, I-00133 Rome, Italy
[3] Univ Aarhus, Inst Storage Ring Facil, DK-8000 Aarhus C, Denmark
[4] Univ Aarhus, Interdisciplinary Nanosci Ctr iNANO, DK-8000 Aarhus C, Denmark
[5] Comis Nacl Energia Atom, Ctr Atom Bariloche, RA-8400 San Carlos De Bariloche, Rio Negro, Argentina
[6] Comis Nacl Energia Atom, Inst Balseiro, RA-8400 San Carlos De Bariloche, Rio Negro, Argentina
关键词
D O I
10.1103/PhysRevB.76.153408
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The combination of the two-dimensional layered structure and the semimetallic character of graphite is expected to produce a C 1s photoemission spectrum of the (0001) surface with only one highly symmetric component. This simple view has been challenged by a recent study, performed on highly oriented pyrolytic graphite (HOPG), in which the existence of two components separated by 120 meV has been reported [T. Balasubramanian et al., Phys. Rev. B 64, 205420 (2001)]. Since HOPG is not perfectly crystalline, in this study, we present a comparison of high-resolution C 1s spectra measured in HOPG, natural graphite crystals, and crystalline graphite films grown on 6H-SiC(0001). Our results demonstrate clearly that the spectrum in graphite (0001) has just one component; the second component at 120 meV is observed only in HOPG and must, therefore, be associated with defects present in this not perfectly crystalline material.
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页数:4
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