Preparation and catalytic properties of resin bound binuclear rhodium tetracarboxylate complexes.

被引：14

作者：

Andersen, JAM

Karodia, N

Miller, DJ

Stones, D

Gani, D

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Univ St Andrews, Ctr Biomol Sci, St Andrews KY16 9ST, Fife, Scotland

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 42期

关键词：

D O I：

10.1016/S0040-4039(98)01709-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

4-(4'-Polystyrylmethyloxy)-3-carboxylatomethyloxy-1-phenylacetate bis-mu-coordinated rhodium(II) diacetate complex, a resin-bound analogue of dirhodium tetraacetate in which two adjacent mu-bridging acetate moieties are covalently linked, serves as an efficient, stable and re-useable immobilised alkene hydrofomylation and hydrogenation catalyst. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：7815 / 7818

页数：4

共 9 条

[1]

Andersen J. M., 1997, PLATIN MET REV, V41, P132

[2] Improved regioselectivity in the hydroformylation reaction catalysed by zeolite-encapsulated rhodium(I) species [J].