From Conception to Realization: An Historial Account of Graphene and Some Perspectives for Its Future

被引:610
作者
Dreyer, Daniel R. [3 ]
Ruoff, Rodney S. [1 ,2 ]
Bielawski, Christopher W. [3 ]
机构
[1] Univ Texas Austin, Dept Mech Engn, Austin, TX 78712 USA
[2] Univ Texas Austin, Texas Mat Inst, Austin, TX 78712 USA
[3] Univ Texas Austin, Dept Chem & Biochem, Austin, TX 78712 USA
基金
美国国家科学基金会;
关键词
carbon; graphene; graphite; history of chemistry; GRAPHITE-INTERCALATION COMPOUNDS; LIQUID-PHASE EXFOLIATION; LARGE-AREA; FUNCTIONALIZED GRAPHENE; MECHANICAL-PROPERTIES; AQUEOUS DISPERSIONS; CHEMICAL-SYNTHESIS; GAS MOLECULES; 111; SURFACE; CARBON;
D O I
10.1002/anie.201003024
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
There has been an intense surge in interest in graphene during recent years. However, graphene-like materials derived from graphite oxide were reported in 1962, and related chemical modifications of graphite were described as early as 1840. In this detailed account of the fascinating development of the synthesis and characterization of graphene, we hope to demonstrate that the rich history of graphene chemistry laid the foundation for the exciting research that continues to this day. Important challenges remain, however; many with great technological relevance. A transformation for the ages: There has been a surge in interest in graphene in recent years; however, graphene-like materials derived from graphite oxide were reported in 1962, and related chemical modifications of graphite were described as early as 1840. This account reveals that the rich history of graphene chemistry, the development of its synthesis and characterization, has laid the foundation for research that continues to this day. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:9336 / 9344
页数:9
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