Kinetics of charge inversion

被引:12
作者
Levin, Y [1 ]
Arenzon, JJ [1 ]
机构
[1] Univ Fed Rio Grande do Sul, Inst Fis, BR-91501970 Porto Alegre, RS, Brazil
来源
JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL | 2003年 / 36卷 / 22期
关键词
D O I
10.1088/0305-4470/36/22/305
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Colloidal suspensions and polyelectrolyte solutions containing multivalent counterions can exhibit some very counter-intuitive behaviour usually associated with low-temperature physics. There are two particularly striking phenomena resulting from strong electrostatic correlations. One is the like-charge attraction and the second is the polyion overcharging. In this contribution we will concentrate on the problem of overcharging. In particular, we will explore the kinetic limitation to colloidal charge inversion in suspensions containing multivalent counterions.
引用
收藏
页码:5857 / 5863
页数:7
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