Catalytic Generation of Hydrogen from Formic acid and its Derivatives: Useful Hydrogen Storage Materials

被引：370

作者：

Loges, Bjoern ^{[1
]}

Boddien, Albert ^{[1
]}

Gaertner, Felix ^{[1
]}

Junge, Henrik ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

TOPICS IN CATALYSIS | 2010年 / 53卷 / 13-14期

关键词：

Formic acid; Hydrogen; Hydrogen storage; Energy; Catalysis; Ruthenium; Carbon dioxide; ASYMMETRIC TRANSFER HYDROGENATION; CARBON-DIOXIDE; PHOTOCHEMICAL DISPLACEMENT; RUTHENIUM COMPLEX; AQUEOUS-SOLUTION; BENZENE LIGAND; AQUA COMPLEXES; DECOMPOSITION; CO2; FORMATE;

D O I：

10.1007/s11244-010-9522-8

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

In this account the concept of using formic acid as a hydrogen storage material is presented. Catalytic reduction of carbon dioxide and heterogeneously catalyzed decomposition of formic acid to hydrogen and carbon dioxide are briefly discussed. In the main part the historic development and recent examples of homogeneously catalyzed hydrogen generation from formic acid are covered in detail.

引用

页码：902 / 914

页数：13

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