Chemical hydrides: A solution to high capacity hydrogen storage and supply

被引:340
作者
Biniwale, Rajesh B. [1 ]
Rayalu, S. [1 ]
Devotta, S. [1 ]
Ichikawa, M. [2 ]
机构
[1] Natl Environm Engn Res Inst, Nagpur 440020, Maharashtra, India
[2] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido, Japan
关键词
hydrogen storage; liquid organic hydrides; delivery to fuelling station; cycloalkanes;
D O I
10.1016/j.ijhydene.2007.07.028
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Cycloalkanes are good candidate media for hydrogen storage (6.5 wt% and 60-62 kg H-2/m(3)). A novel approach for the supply of hydrogen, through liquid organic hydrides (LOH) using catalytic reaction pair of dehydrogenation of cycloalkanes and hydrogenation of corresponding aromatics is a useful process for supply of hydrogen. Hydrogenation of aromatics is relatively well-established process. However, the efforts are needed to develop efficient catalyst for dehydrogenation of cycloalkanes. In this paper we review the dehydrogenation of cycloalkanes as useful reaction for storage of hydrogen in chemical hydrides. (C) 2007 International Association for Hydrogen Energy. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:360 / 365
页数:6
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