Measurement and modeling of the CO2 solubility in poly(ethylene glycol) of different molecular weights

被引：58

作者：

Aionicesei, Elena ^{[1
]}

Skerget, Mojca ^{[1
]}

Knez, Zeljko ^{[1
]}

机构：

[1] Univ Maribor, Fac Chem & Chem Engn, Lab Separat Proc, SI-2000 Maribor, Slovenia

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2008年 / 53卷 / 01期

关键词：

D O I：

10.1021/je700467p

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The solubility of supercritical carbon dioxide (ScCO2) in solid (298 K) and melted (323 K) poly(ethylene glycol) (PEG), in the pressure range (7 to 25) MPa, was measured using a magnetic suspension balance. The phase behavior of the CO2 + PEG system was modeled by using the Sanchez-Lacombe equation of state (EOS) and statistical associating fluid theory (SAFT). The results show a good solubility of CO2 in polymer and a good accuracy of the thermodynamic models in describing the phase equilibrium of the working system. The experimental data are also in good agreement with the solubility values previously described in the literature, obtained by employing different experimental techniques.

引用

页码：185 / 188

页数：4

共 29 条

[11] EQUATION OF STATE FOR SMALL, LARGE, POLYDISPERSE, AND ASSOCIATING MOLECULES - EXTENSION TO FLUID MIXTURES [J].

HUANG, SH ;

RADOSZ, M .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1991, 30 (08) :1994-2005

[12] EQUATION OF STATE FOR SMALL, LARGE, POLYDISPERSE, AND ASSOCIATING MOLECULES [J].

HUANG, SH ;

RADOSZ, M .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1990, 29 (11) :2284-2294

[13]

Kazarian S.G., 2000, POLYM SCI SER C+, V42, P78, DOI DOI 10.1080/03602549909351647

[14] Matrices and scaffolds for delivery of bioactive molecules in bone and cartilage tissue engineering [J].

Lee, Soo-Hong ;

Shin, Heungsoo .

ADVANCED DRUG DELIVERY REVIEWS, 2007, 59 (4-5) :339-359

[15] Phase behavior of CO2 plus polyethylene glycol plus ethanol at pressures up to 20 MPa [J].

Matsuyama, Kiyoshi ;

Mishima, Kenji .

FLUID PHASE EQUILIBRIA, 2006, 249 (1-2) :173-178

[16] Processing of carbamazepine PEG 4000 solid dispersions with supercritical carbon dioxide: preparation, characterisation, and in vitro dissolution [J].

Moneghini, M ;

Kikic, I ;

Voinovich, D ;

Perissutti, B ;

Filipovic-Grcic, J .

INTERNATIONAL JOURNAL OF PHARMACEUTICS, 2001, 222 (01) :129-138

[17] Batch production of micron size particles from poly(ethylene glycol) using supercritical CO2 as a processing solvent [J].

Nalawade, Sameer P. ;

Picchioni, Francesco ;

Janssen, L. P. B. M. .

CHEMICAL ENGINEERING SCIENCE, 2007, 62 (06) :1712-1720

[18] Supercritical carbon dioxide as a green solvent for processing polymer melts: Processing aspects and applications [J].

Nalawade, SP ;

Picchioni, F ;

Janssen, LPBM .

PROGRESS IN POLYMER SCIENCE, 2006, 31 (01) :19-43

[19] Supercritical fluid technologies and tissue engineering scaffolds [J].

Quirk, RA ;

France, RM ;

Shakesheff, KM ;

Howdle, SM .

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2004, 8 (3-4) :313-321

[20]

Reverchon E, 2003, CURR OPIN SOLID ST M, V7, P391, DOI 10.1016/j.cossms.2003.01.002

← 1 2 3 →