Enhancement of luminescence intensity in TMPY/perylene co-single crystals

被引:32
作者
Li, Jinpeng [1 ]
Takaishi, Shinya [1 ]
Fujinuma, Naohiro [1 ]
Endo, Katsutoshi [1 ]
Yamashita, Masahiro [1 ]
Matsuzaki, Hiroyuki [2 ,3 ]
Okamoto, Hiroshi [2 ,3 ]
Sawabe, Kosuke [5 ]
Takenobu, Taishi [4 ,6 ]
Iwasa, Yoshihiro [7 ]
机构
[1] Tohoku Univ, Dept Chem, Grad Sch Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan
[2] Univ Tokyo, Dept Adv Mat Sci, Chiba, Japan
[3] Japan Sci & Technol Agcy JST, CREST, Tokyo, Japan
[4] Waseda Univ, Dept Appl Phys, Tokyo, Japan
[5] Tohoku Univ, Grad Sch Sci, Dept Phys, Sendai, Miyagi 9808578, Japan
[6] Japan Sci & Technol Agcy JST, PRESTO, Saitama, Japan
[7] Univ Tokyo, Dept Appl Phys, Grad Sch Engny, Tokyo 113, Japan
关键词
FIELD-EFFECT TRANSISTORS; EMISSION; ELECTROLUMINESCENCE; RECOMBINATION; TRANSPORT; POLYMERS; DIODE;
D O I
10.1039/c1jm12977e
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new molecule, 1,3,6,8-tetramethylpyrene (TMPY), with a similar shape to the luminescent material perylene has been successfully synthesized. The co-crystals with perylene doping have been grown and their crystal structure has been clarified by X-ray analysis. Optical spectra indicate that effective energy transfer has been achieved in the doping systems and the luminescence efficiency has reached as high as 78%. The pure TMPY shows p-type characteristics during the FET operation. The hole mobility is up to 0.26 cm(2) V-1 s(-1).
引用
收藏
页码:17662 / 17666
页数:5
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