One-dimensional oxalato-bridged copper(II) complex possessing two structurally different metallic centres

被引：40

作者：

Castillo, O

Luque, A

Lloret, F

Román, P

机构：

[1] Univ Basque Country, Dept Quim Inorgan, E-48080 Bilbao, Spain

[2] Univ Valencia, Fac Quim, Dept Quim Inorgan, E-46100 Valencia, Spain

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2001年 / 4卷 / 07期

关键词：

oxalato bridge; polynuclear complex; copper complex; antiferromagnetic coupling; crystal structure;

D O I：

10.1016/S1387-7003(01)00209-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of the oxalato-bridged copper(II) compound [Cu-2(mu -ox)(2)(ampy)(3)](n) 1 (ox=oxalate dianion, ampy=2-amino-3-methylpyridine) consists of infinite corrugated one-dimensional chains in which two types of copper(II) centres, five- and six-coordinated, are bridged sequentially by asymmetric bis-bidentate oxalato ligands. Magnetic susceptibility measurements show the occurrence of a significant intrachain antiferromagnetic coupling (J = -22.9 cm(-1)). (C) 2001 Elsevier Science B.V. All rights reserved.

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页码：350 / 353

页数：4

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