Control of chiral ordering in aggregated poly{3-(S)-[2-methylbutyl]thiophene} by a doping-dedoping process

被引：17

作者：

Zhang, ZB

Fujiki, M

Motonaga, M

McKenna, CE

机构：

[1] CREST, JST, Nara 6300101, Japan

[2] NAIST, Grad Sch Mat Sci, Adv Polymer Sci Lab, Nara 6300101, Japan

[3] Univ So Calif, Dept Chem, Los Angeles, CA 90089 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 26期

关键词：

D O I：

10.1021/ja029220y

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The chiral ordering in aggregated poly(3-alkylthiophene) can be controlled by a metal salt-dependent doping-dedoping process. Enhancement or reduction in the chiral anisotropy factor depends on the doping level, such that doping driven by polymer-metal salt interactions, and dedoping driven by aggregate formation must be balanced in order to achieve maximal chiral ordering. This phenomenon provides a new basis to control chiral arrangement in conjugated polymer aggregates, relying solely on doping, and thus avoiding tedious modification of side-chain or main-chain structures.

引用

页码：7878 / 7881

页数：4